Porous Double-Walled Metal Triazolate Framework Based upon a Bifunctional Ligand and a Pentanuclear Zinc Cluster Exhibiting Selective CO2 Uptake

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• 作者：Wen-Yang Gao ; Wuming Yan ; Rong Cai ; Le Meng ; Andrea Salas ; Xi-Sen Wang ; Lukasz Wojtas ; Xiaodong Shi ; Shengqian Ma
• 刊名：Inorganic Chemistry
• 出版年：2012
• 出版时间：April 16, 2012
• 年：2012
• 卷：51
• 期：8
• 页码：4423-4425
• 全文大小：215K
• 年卷期：v.51,no.8(April 16, 2012)
• ISSN：1520-510X

文摘

The self-assembly of a custom-designed bifunctional ligand featuring both 1,2,3-triazolate and carboxylate donor groups with a pentanuclear zinc cluster generated in situ affords a double-walled metal triazolate framework (MTAF) material, MTAF-1 (Zn₅(渭₃-O)₂(C₉N₃H₅O₂)₅(H⁺)₄(H₂O)₁₇(C₃H₇NO)₁₀), which exhibits a surface area of 2300 m²/g and demonstrates interesting selective CO₂ uptake performances.