Low Electric Field Intensity and Thermotropic Tuning Surface Plasmon Band Shift of Gold Island Film by Liquid Crystals

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• 作者：Jing Xie ; Xuemin Zhang ; Zenghui Peng ; Zhanhua Wang ; Tieqiang Wang ; Shoujun Zhu ; Zhaoyi Wang ; Liang Zhang ; Junhu Zhang ; Bai Yang
• 刊名：The Journal of Physical Chemistry C
• 出版年：2012
• 出版时间：February 2, 2012
• 年：2012
• 卷：116
• 期：4
• 页码：2720-2727
• 全文大小：438K
• 年卷期：v.116,no.4(February 2, 2012)
• ISSN：1932-7455

文摘

By applying an electric field to nematic liquid crystals (LCs) to change the molecular alignment of LCs, we achieve feasible tuning of the localized surface plasmon resonance (LSPR) of novel gold island film immersed in the LCs, realizing the switching behavior of LSPR at low electric field intensity. In addition, we find that the liquid crystal can amplify the angle dependence of gold island film LSPR, which may provide a new method for research on the tiny and indistinct change of the gold nanoparticles鈥?LSPR. At the same time, the LSPR can be used for detection of nematic LCs鈥?thermal鈥搊ptic effect, especially when the temperature is around the clearing point. For the entire experimental procedure, self-assembly and experimental tests are simple and require only common laboratory supplies and equipment, and both of them are novel relative to previous studies, which help us further investigate coupling the metal nanoparticles with the LCs.