One-Pot, Green, Rapid Synthesis of Flowerlike Gold Nanoparticles/Reduced Graphene Oxide Composite with Regenerated Silk Fibroin As Efficient Oxygen Reduction Electrocatalysts

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• 作者：Shengjie Xu ; Liu Yong ; Peiyi Wu
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2013
• 出版时间：February 13, 2013
• 年：2013
• 卷：5
• 期：3
• 页码：654-662
• 全文大小：531K
• 年卷期：v.5,no.3(February 13, 2013)
• ISSN：1944-8252

文摘

Flowerlike gold nanoparticles (Au NPs)/reduced graphene oxide (RGO) composites were fabricated by a facile, one-pot, environmentally friendly method in the presence of regenerated silk fibroin (RSF). The influences of reaction time, temperature, and HAuCl₄: RGO ratio on the morphology of Au NPs loaded on RGO sheets were discussed and a tentative mechanism for the formation of flowerlike Au NPs/RGO composite was proposed. In addition, the flowerlike Au NPs/RGO composite showed superior catalytic performance for oxygen reduction reaction (ORR) to Au/RGO composites with other morphologies. Our work provides an alternative facile and green approach to synthesize functional metal/RGO composites.

Keywords:

flowerlike Au NPs; regenerated silk fibroin; graphene; electro-catalysis; oxygen reduction