Formation of [NiIII(魏1-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)]鈭?/sup> via CS2 Insertion into Nickel(III) Hydr

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• 作者：Kuan-Ting Lai ; Wei-Chieh Ho ; Tzung-Wen Chiou ; Wen-Feng Liaw
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：April 15, 2013
• 年：2013
• 卷：52
• 期：8
• 页码：4151-4153
• 全文大小：205K
• 年卷期：v.52,no.8(April 15, 2013)
• ISSN：1520-510X

文摘

Insertion of CS₂ into the thermally unstable nickel(III) hydride [PPN][Ni(H)(P(o-C₆H₃-3-SiMe₃-2-S)₃)] (1), freshly prepared from the reaction of [PPN][Ni(OC₆H₅)P(C₆H₃-3-SiMe₃-2-S)₃] and 4,4,5,5-tetramethyl-1,3,2-dioxaborolane (HBpin; pin = OCMe₂CMe₂O) in tetrahydrofuran at 鈭?0 掳C via a metathesis reaction, readily affords [PPN][Ni^III(魏¹-S₂CH)(P(o-C₆H₃-3-SiMe₃-2-S)₃)] (2) featuring a 魏¹-S₂CH moiety.