Iron in a Trigonal Tris(alkoxide) Ligand Environment
详细信息 查看全文
- 作者：Matthew B. Chambers ; Stanislav Groysman ; Dino Villagr谩n ; Daniel G. Nocera
- 刊名：Inorganic Chemistry
- 出版年：2013
- 出版时间：March 18, 2013
- 年：2013
- 卷：52
- 期：6
- 页码：3159-3169
- 全文大小：430K
- 年卷期：v.52,no.6(March 18, 2013)
- ISSN：1520-510X
文摘
Mononuclear Fe(II) and Fe(III) complexes residing in a trigonal tris(ditox) (ditox = tBu2(Me)CO鈥?/sup>) ligand environment have been synthesized and characterized. The Fe(III) ditox complex does not react with oxidants such as PhIO, whereas NMe3O substitutes a coordinated tetrahydrofuran (THF) in the apical position without undergoing oxo transfer. In contrast, the Fe(II) ditox complex reacts rapidly with PhIO or Me3NO in THF or cyclohexadiene to furnish a highly reactive intermediate, which cleaves C鈥揌 bonds to afford the Fe(III)鈥揾ydroxide complex. When generated in 1,2-difluorobenze, this intermediate can be intercepted to oxidize phosphines to phosphine oxide. The fast rates at which these reactions occur is attributed to a particularly weak ligand field imparted by the tris(alkoxide) ancillary ligand environment.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |