Electronegativity, Charge Transfer, Crystal Field Strength, and the Point Charge Model Revisited
详细信息 查看全文
- 作者：Peter A. Tanner ; Lixin Ning
- 刊名：The Journal of Physical Chemistry A
- 出版年：2013
- 出版时间：February 21, 2013
- 年：2013
- 卷：117
- 期：7
- 页码：1503-1507
- 全文大小：371K
- 年卷期：v.117,no.7(February 21, 2013)
- ISSN：1520-5215
文摘
Although the optical spectra of LnCl63鈥?/sup> systems are complex, only two crystal field parameters, B40 and B60, are required to model the J-multiplet crystal field splittings in octahedral symmetry. It is found that these parameters exhibit R鈥? and R鈥? dependence, respectively, upon the ionic radius Ln3+(VI), but not upon the Ln鈥揅l distance. More generally, the crystal field strengths of LnX6 systems (X = Br, Cl, F, O) exhibit linear relationships with ligand electronegativity, charge transfer energy, and fractional ionic character of the Ln鈥揦 bond.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |