A Method for Synthesis of Homoallylic Bromide

详细信息    查看全文

• 作者：Wenke Qi ; Peipei Wang ; Liyuan Fan ; Songlin Zhang
• 刊名：The Journal of Organic Chemistry
• 出版年：2013
• 出版时间：June 21, 2013
• 年：2013
• 卷：78
• 期：12
• 页码：5918-5924
• 全文大小：311K
• 年卷期：v.78,no.12(June 21, 2013)
• ISSN：1520-6904

文摘

Cyclopropyl Grignard reagents react with carbonyl compounds in the presence of diethyl phosphite to give homoallylic bromides. The reaction is effectively carried out under mild conditions in a one-pot fashion with moderate to good yields.