Perspective of Positron Annihilation Spectroscopy in Polymers

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• 作者：Y. C. Jean ; J. David Van Horn ; Wei-Song Hung ; Kuier-Rarn Lee
• 刊名：Macromolecules
• 出版年：2013
• 出版时间：September 24, 2013
• 年：2013
• 卷：46
• 期：18
• 页码：7133-7145
• 全文大小：681K
• 年卷期：v.46,no.18(September 24, 2013)
• ISSN：1520-5835

文摘

Positron annihilation spectroscopy (PAS) is a novel method that provides molecular-level information about complex macromolecular structure in a manner different from, but complementary to, conventional physical and chemical methodology. This paper presents a perspective of PAS in polymeric systems covering 12 aspects: historical, spacial, spherical quantum model, anisotropic structure, voids, positronium chemistry, time, positron annihilation lifetime spectroscopy and data analysis, variable monoenergetic slow positron beam techniques and depth profiling, elemental analysis, multidimensional instrumentation advances in PAS, and free volume and free-volume theories.