Porous Zirconium Metal鈥揙rganic Framework Constructed from 2D 鈫?3D Interpenetration Based on a 3,6-Connected kgd Net

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• 作者：Rongming Wang ; Zhiying Wang ; Yuwen Xu ; Fangna Dai ; Liangliang Zhang ; Daofeng Sun
• 刊名：Inorganic Chemistry
• 出版年：2014
• 出版时间：July 21, 2014
• 年：2014
• 卷：53
• 期：14
• 页码：7086-7088
• 全文大小：212K
• ISSN：1520-510X

文摘

A new porous zirconium metal鈥搊rganic framework (Zr MOF), Zr₆(渭₃-O)₄(渭₃-OH)₄(OH)₆(H₂O)₆(BTB)₂路6DMF路H₂O (1; H₃BTB = 5鈥?(4-carboxyphenyl)[1,1鈥?3鈥?1鈥?terphenyl]-4,4鈥?dicarboxylic acid), based on Zr₆ clusters and tricarboxylate ligands has been constructed and characterized. The Zr₆ clusters were linked by BTB ligands to generate a 2D network of kgd topology. The interpenetrations among the 2D networks gave rise to a 3D porous framework, which represents the first Zr MOF constructed from 2D 鈫?3D interpenetration. The gas uptake and catalytic properties for 1 have also been studied.