Electrospun TiO2鈭捨?/sub> Nanofibers as Insertion Anode for Li-Ion Battery Applications

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• 作者：Jayaraman Sundaramurthy ; Vanchiappan Aravindan ; Palaniswamy Suresh Kumar ; Srinivasan Madhavi ; Seeram Ramakrishna
• 刊名：Journal of Physical Chemistry C
• 出版年：2014
• 出版时间：July 31, 2014
• 年：2014
• 卷：118
• 期：30
• 页码：16776-16781
• 全文大小：470K
• ISSN：1932-7455

文摘

A scalable electrospinning technique is used to synthesize 1D TiO₂ nanofibers for Li-ion battery applications. Oxygen deficiency (TiO_{2鈭捨?/sub>) in anatase phases is created by treating the nanofibers in the H2 atmosphere with various temperature conditions. Structural and morphological features of both pure and oxygen deficient phases are analyzed by X-ray diffraction and scanning electron microscopy, respectively. Li-insertion properties of such nanofibers are evaluated in half-cell configuration at high current rate of 150 mA g^鈥? and found that there is no improvement in the reversible capacity after H2 treatment. Improved cycling profiles are noted for such deficient phases compared with pure TiO2 nanofibers. ac impedance spectra were also conducted to validate the electrical conductivity profiles of the electrospun TiO2 nanofibers.}