Quantitative Evaluation on Activated Property-Tunable Bulk Liquid Water with Reduced Hydrogen Bonds Using Deconvoluted Raman Spectroscopy

详细信息    查看全文

• 作者：Hsiao-Chien Chen ; Fu-Der Mai ; Kuang-Hsuan Yang ; Liang-Yih Chen ; Chih-Ping Yang ; Yu-Chuan Liu
• 刊名：Analytical Chemistry
• 出版年：2015
• 出版时间：January 6, 2015
• 年：2015
• 卷：87
• 期：1
• 页码：808-815
• 全文大小：513K
• ISSN：1520-6882

文摘

Interesting properties of water with distinguishable hydrogen-bonding structure on interfacial phase or in confined environment have drawn wide attentions. However, these unique properties of water are only found within the interfacial phase and confined environment, thus, their applications are limited. In addition, quantitative evaluation on these unique properties associating with the enhancement of water鈥檚 physical and chemical activities represents a notable challenge. Here we report a practicable production of free-standing liquid water at room temperature with weak hydrogen-bonded structure naming Au nanoparticles (NPs)-treated (AuNT) water via treating by plasmon-induced hot electron transfer occurred on resonantly illuminated gold NPs (AuNPs). Compared to well-known untreated bulk water (deionized water), the prepared AuNT water exhibits many distinct activities in generally physical and chemical reactions, such as high solubilities to NaCl and O₂. Also, reducing interaction energy within water molecules provides lower overpotential and higher efficiency in electrolytic hydrogen production. In addition, these enhanced catalytic activities of AuNT water are tunable by mixing with deionized water. Also, most of these tunable activities are linearly proportional to its degree of nonhydrogen-bonded structure (DNHBS), which is derived from the O鈥揌 stretching in deconvoluted Raman spectrum.