Coassembly-Directed Fabrication of an Exfoliated Form of Alternating Multilayers Composed of a Self-assembled Organoplatinum(II) Complex鈥揊ullerene Dyad

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• 作者：Satoru Sato ; Toshiaki Takei ; Yoshitaka Matsushita ; Takeshi Yasuda ; Tatsuhiro Kojima ; Masaki Kawano ; Masato Ohnuma ; Kentaro Tashiro
• 刊名：Inorganic Chemistry
• 出版年：2015
• 出版时间：December 21, 2015
• 年：2015
• 卷：54
• 期：24
• 页码：11581-11583
• 全文大小：242K
• ISSN：1520-510X

文摘

The self-assembly of covalently linked dyad 1a of cyclometalated organoplatinum(II) complex and fullerene afforded alternating multilayers of electron-rich and -deficient molecular components. On the other hand, the coassembly of 1a with organoplatinum(II) complex 2 having no fullerene moiety gave an exfoliated form of the multilayers, by inhibiting the interdigitation of organoplatinum(II) complex moieties of 1a. The coassembled 1a/2 transports both of the photogenerated holes and electrons, while the self-assembled 1a allows only the transportation of electrons under the same conditions.