Multifunctional Fullerene Derivative for Interface Engineering in Perovskite Solar Cells

详细信息    查看全文

• 作者：Yaowen Li ; Yue Zhao ; Qi Chen ; Yang (Michael) Yang ; Yongsheng Liu ; Ziruo Hong ; Zonghao Liu ; Yao-Tsung Hsieh ; Lei Meng ; Yongfang Li ; Yang Yang
• 刊名：Journal of the American Chemical Society
• 出版年：2015
• 出版时间：December 16, 2015
• 年：2015
• 卷：137
• 期：49
• 页码：15540-15547
• 全文大小：563K
• ISSN：1520-5126

文摘

In perovskite based planar heterojunction solar cells, the interface between the TiO₂ compact layer and the perovskite film is critical for high photovoltaic performance. The deep trap states on the TiO₂ surface induce several challenging issues, such as charge recombination loss and poor stability etc. To solve the problems, we synthesized a triblock fullerene derivative (PCBB-2CN-2C8) via rational molecular design for interface engineering in the perovskite solar cells. Modifying the TiO₂ surface with the compound significantly improves charge extraction from the perovskite layer. Together with its uplifted surface work function, open circuit voltage and fill factor are dramatically increased from 0.99 to 1.06 V, and from 72.2% to 79.1%, respectively, resulting in 20.7% improvement in power conversion efficiency for the best performing devices. Scrutinizing the electrical properties of this modified interfacial layer strongly suggests that PCBB-2CN-2C8 passivates the TiO₂ surface and thus reduces charge recombination loss caused by the deep trap states of TiO₂. The passivation effect is further proven by stability testing of the perovskite solar cells with shelf lifetime under ambient conditions improved by a factor of more than 4, from 鈭?0 h to 鈭?00 h, using PCBB-2CN-2C8 as the TiO₂ modification layer. This work offers not only a promising material for cathode interface engineering, but also provides a viable approach to address the challenges of deep trap states on TiO₂ surface in planar perovskite solar cells.