Phosphine Gas Adsorption in a Series of Metal鈥揙rganic Frameworks

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• 作者：Mitchell H. Weston ; William Morris ; Paul W. Siu ; William J. Hoover ; David Cho ; Rachelle K. Richardson ; Omar K. Farha
• 刊名：Inorganic Chemistry
• 出版年：2015
• 出版时间：September 8, 2015
• 年：2015
• 卷：54
• 期：17
• 页码：8162-8164
• 全文大小：237K
• ISSN：1520-510X

文摘

For the first time, phosphine adsorption has been evaluated in a series of metal鈥搊rganic frameworks (MOFs). Open-metal coordination sites were found to significantly enhance the ability of MOFs to adsorb highly toxic phosphine gas, with the identity of the open-metal site also modulating the amount of gas adsorbed. The MOFs studied outperform activated carbon, a commonly used material to capture phosphine.