Orthogonal Ternary Functionalization of a Mesoporous Metal鈥揙rganic Framework via Sequential Postsynthetic Ligand Exchange

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• 作者：Chong Liu ; Tian-Yi Luo ; Evan S. Feura ; Chen Zhang ; Nathaniel L. Rosi
• 刊名：Journal of the American Chemical Society
• 出版年：2015
• 出版时间：August 26, 2015
• 年：2015
• 卷：137
• 期：33
• 页码：10508-10511
• 全文大小：378K
• ISSN：1520-5126

文摘

A sequential postsynthetic ligand exchange process was used to prepare a series of mono-, di-, and trifunctionalized mesoporous metal鈥搊rganic frameworks (MOFs). Using this process, orthogonal functional groups were installed and thereafter postsynthetically modified with dye and quencher molecules. Microspectrophotometry studies were used to determine the distribution of the two orthogonal functional groups within the MOF crystals.