Low Pressure CO2 Hydrogenation to Methanol over Gold Nanoparticles Activated on a CeOx/TiO2 Interface

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• 作者：Xiaofang Yang ; Shyam Kattel ; Sanjaya D. Senanayake ; J. Anibal Boscoboinik ; Xiaowa Nie ; Jes煤s Graciani ; Jos茅 A. Rodriguez ; Ping Liu ; Dar铆o J. Stacchiola ; Jingguang G. Chen
• 刊名：Journal of the American Chemical Society
• 出版年：2015
• 出版时间：August 19, 2015
• 年：2015
• 卷：137
• 期：32
• 页码：10104-10107
• 全文大小：342K
• ISSN：1520-5126

文摘

Capture and recycling of CO₂ into valuable chemicals such as alcohols could help mitigate its emissions into the atmosphere. Due to its inert nature, the activation of CO₂ is a critical step in improving the overall reaction kinetics during its chemical conversion. Although pure gold is an inert noble metal and cannot catalyze hydrogenation reactions, it can be activated when deposited as nanoparticles on the appropriate oxide support. In this combined experimental and theoretical study, it is shown that an electronic polarization at the metal鈥搊xide interface of Au nanoparticles anchored and stabilized on a CeO_x/TiO₂ substrate generates active centers for CO₂ adsorption and its low pressure hydrogenation, leading to a higher selectivity toward methanol. This study illustrates the importance of localized electronic properties and structure in catalysis for achieving higher alcohol selectivity from CO₂ hydrogenation.