Development and Application of O-(Trimethylsilyl)aryl Fluorosulfates for the Synthesis of Arynes

详细信息    查看全文

• 作者：Qiao Chen ; Hongmei Yu ; Zhaoqing Xu ; Li Lin ; Xianxing Jiang ; Rui Wang
• 刊名：Journal of Organic Chemistry
• 出版年：2015
• 出版时间：July 2, 2015
• 年：2015
• 卷：80
• 期：13
• 页码：6890-6896
• 全文大小：405K
• ISSN：1520-6904

文摘

A class of o-(trimethylsilyl)aryl fluorosulfates was synthesized by a concise method and successfully used as aryne precursors for the first time. Different trapping agents such as azides, furans, and acyl acetoacetates could successfully react with the aryne precursors under mild conditions with good to excellent yields.