Formation of An Ionic PTCA-尾-CDNH2 Complex and Its Application for Phenol Sensing in Aqueous Phase

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• 作者：Lingling Liu ; Xiangli Chen ; Kaiqiang Liu ; Meixia He ; Gang Wang ; Xingmao Chang ; Yu Fang
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2015
• 出版时间：September 30, 2015
• 年：2015
• 卷：7
• 期：38
• 页码：21364-21372
• 全文大小：524K
• ISSN：1944-8252

文摘

On the basis of proton transfer in aqueous phase, we prepared a water-soluble and highly fluorescent ionic complex of 3,4,9,10-perylene tetracarboxylic acid (PTCA) and 6-deoxy-6-amino-尾-CD (尾-CDNH₂) and studied its fluorescence behavior. It was found that the fluorescence emission of the complex is sensitive and selective to the presence of trace amount of toxic phenolic compounds, in particular phenol, which is crucial for water quality control. The detection limit (DL) of the method to the analyte is 鈭?.03 渭M, a lowest value reported in literatures for similar techniques. Interestingly, the detection at an unprecedented subnanogram (DL, 鈭?.12 ng/cm²) level can also be conducted in a visualized manner, which may provide a simple and low-cost protocol for on-site and real-time detection of the analyte. Moreover, the complex is humidity sensitive in dry state, and its color changes from bright yellow to bright green when exposed to wet vapor. Unlike other PTCA bisimide derivatives, preparation of the ionic complex of PTCA/尾-CDNH₂ is simple and avoids complicated synthetic burden. Furthermore, introduction of methanol into the aqueous solution of the complex resulted in aggregation as indicated by solution color change and proved by transmission electron microscopy and dynamic light scattering studies, which explains why the compound in dry state is sensitive to the presence of water and water vapor. X-ray diffraction, UV鈥搗is, and fluorescence studies uncovered the H-packing nature of the structure of the aggregate.