Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups

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• 作者：Donghai An ; Qingrong Kong ; Min Zhang ; Yun Yang ; Danni Li ; Zhihua Yang ; Shilie Pan ; Huimin Chen ; Zhi Su ; Yi Sun ; Miriding Mutailipu
• 刊名：Inorganic Chemistry
• 出版年：2016
• 出版时间：January 19, 2016
• 年：2016
• 卷：55
• 期：2
• 页码：552-554
• 全文大小：305K
• ISSN：1520-510X

文摘

Three new alkali-metal mixed borates, LiNaB₈O₁₃, α-LiKB₈O₁₃, and β-LiKB₈O₁₃, containing a ³_∞[B₈O₁₃] three-dimensional network have been successfully synthesized. Their fundamental building block is [B₈O₁₆]^8– formed by the vertex-sharing [B₅O₁₀]^5– and [B₃O₇]^5– groups, which are topologically identical when they are considered as four-connected nodes. The viewpoints give us a feasible way to investigate the versatile structure assembly of borates with a complex network.