Catalytic and Atom-Economic Intermolecular Amidoselenenylation of Alkenes

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• 作者：E Tang ; Weilin Wang ; Yinjiao Zhao ; Meng Zhang ; Xin Dai
• 刊名：Organic Letters
• 出版年：2016
• 出版时间：January 15, 2016
• 年：2016
• 卷：18
• 期：2
• 页码：176-179
• 全文大小：395K
• ISSN：1523-7052

文摘

A method for the simple, efficient, and atom-economic amidoselenenylation of simple alkenes under mild conditions using TiCl₄ as a catalyst and N-(phenylseleno)phthalimide as both a nitrogen and selenium source was developed. A broad range of olefins can be applied to afford vicinal amidoselenides in good yield and with high regioselectivity and diastereoselectivity.