Inhibiting Interfacial Recombination Events in Dye-Sensitized Solar Cells using Self-Assembled Bilayers

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• 作者：Omotola O. Ogunsolu ; Jamie C. Wang ; Kenneth Hanson
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2015
• 出版时间：December 23, 2015
• 年：2015
• 卷：7
• 期：50
• 页码：27730-27734
• 全文大小：287K
• ISSN：1944-8252

文摘

The rate and efficiency of electron transfer events at the semiconductor–dye–electrolyte interface is of critical importance to the overall performance of dye-sensitized solar cells (DSSCs) and dye-sensitized photoelectrosynthesis cells. In this work, we introduce self-assembled bilayers composed of a metal oxide electrode, bridging molecules, linking ions, and dye as an effective strategy to manipulate interfacial electron transfer events at the photoanode of DSSCs. Spectroelectrochemical measurements including current–voltage, incident photon-to-current efficiency, and electrochemical impedance spectroscopy are used to quantify interfacial electron transfer and transport events with respect to the length of the bridging molecules. The general trend in increased lifetime and diffusion length in TiO₂ as well as an increase in open circuit voltage with bridge length indicate that the bilayer is an effective strategy in inhibiting the TiO₂(e^–) to redox mediator recombination events. However, the increased separation between the dye and the semiconductor also reduces the electron injection rate resulting in a decrease in photocurrent as the bridge length increases. The observed enhancement in open circuit voltages are far outweighed by the significant decrease in photocurrent and thus overall device performance decreases with increasing bridge length.