Low-Pressure-Assisted Coating Method To Improve Interface between PEDOT:PSS and Silicon Nanotips for High-Efficiency Organic/Inorganic Hybrid Solar Cells via Solution Process

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• 作者：Thiyagu Subramani ; Hong-Jhang Syu ; Chien-Ting Liu ; Chen-Chih Hsueh ; Song-Ting Yang ; Ching-Fuh Lin
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：January 27, 2016
• 年：2016
• 卷：8
• 期：3
• 页码：2406-2415
• 全文大小：596K
• ISSN：1944-8252

文摘

Nanostructured silicon hybrid solar cells are promising candidates for a new generation photovoltaics because of their light-trapping abilities and solution processes. However, the performance of hybrid organic/Si nanostructure solar cells is hindered because of carrier recombination at surface and poor coverage of organic material poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) on nanostructures. Here we demonstrate low-pressure-assisted coating method of PEDOT:PSS on surface-modified silicon nanotips with broadband light-trapping characteristics to improve interface property and to achieve high-efficiency hybrid solar cells through a solution process. The approach enhances the effective minority-carrier lifetime and the coverage of PEDOT:PSS on the surface of nanostructures. Hybrid solar cells fabricated with surface-modified nanotips exhibit a high fill factor of 70.94%, short-circuit current density of 35.36 mA/cm², open-circuit voltage of 0.528 V, and power conversion efficiency of 13.36%. The high efficiency and the high fill factor are achieved because of conformal coating of PEDOT:PSS via a low-pressure-assisted coating process, excellent light harvesting without sacrificing the minority-carrier lifetime, and efficient charge separation/collection of photogenerated carriers.