Physiochemical Characterization of Lignocellulosic Biomass Dissolution by Flowthrough Pretreatment

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• 作者：Lishi Yan ; Yunqiao Pu ; Mark Bowden ; Arthur J. Ragauskas ; Bin Yang
• 刊名：ACS Sustainable Chemistry & Engineering
• 出版年：2016
• 出版时间：January 4, 2016
• 年：2016
• 卷：4
• 期：1
• 页码：219-227
• 全文大小：483K
• ISSN：2168-0485

文摘

Comprehensive understanding of biomass solubilization chemistry in aqueous pretreatment such as water-only and dilute acid flowthrough pretreatment is of fundamental importance to achieve the goal of valorizing biomass to fermentable sugars and lignin for biofuels production. In this study, poplar wood was flowthrough pretreated by water-only or 0.05% (w/w) sulfuric acid at different temperatures (220–270 °C), flow rate (25 mL/min), and reaction times (8–90 min), resulting in significant disruption of the lignocellulosic biomass. Ion chromatography (IC), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) analysis, and solid state cross-polarization/magic angle spinning (CP/MAS) ¹³C nuclear magnetic resonance (NMR) spectroscopy were applied to characterize the pretreated biomass whole slurries in order to reveal depolymerization as well as solubilization mechanism and identify unique dissolution structural features during these pretreatments. Results showed temperature-dependent cellulose decrystallization in flowthrough pretreatment. Crystalline cellulose was completely disrupted, and mostly converted to amorphous cellulose and oligomers by water-only operation at 270 °C for 10 min and by 0.05 wt % H₂SO₄ flowthrough pretreatment at 220 °C for 12 min. Flowthrough pretreatment with 0.05% (w/w) H₂SO₄ led to a greater disruption of structures in pretreated poplar at a lower temperature compared to water-only pretreatment.