Introducing Dimensionality to the Archetypical Mn12 Single-Molecule Magnet: a Family of [Mn12]n Chains

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• 作者：Sergio A. Corrales ; John M. Cain ; Kelley A. Uhlig ; Andrew M. Mowson ; Constantina Papatriantafyllopoulou ; Marcus K. Peprah ; Andrew Ozarowski ; Anastasios J. Tasiopoulos ; George Christou ; Mark W. Meisel ; Christos Lampropoulos
• 刊名：Inorganic Chemistry
• 出版年：2016
• 出版时间：February 15, 2016
• 年：2016
• 卷：55
• 期：4
• 页码：1367-1369
• 全文大小：239K
• ISSN：1520-510X

文摘

The [Mn₁₂O₁₂(O₂CR)₁₆(L₄)] family (R = various; L = terminal ligand) of clusters holds a special place in molecular magnetism; they are the most well-studied single-molecule magnets (SMMs). Targeted linkage of these SMMs has now been achieved for the first time. The resulting chain structures have been confirmed crystallographically, and the magnetic properties, up to 1.14 GPa, and high-field electron paramagnetic resonance spectra have been collected and analyzed.