Cobalt(II)-Catalyzed C–H Amination of Arenes with Simple Alkylamines

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• 作者：Lin-Bao Zhang ; Shou-Kun Zhang ; Donghui Wei ; Xinju Zhu ; Xin-Qi Hao ; Jian-Hang Su ; Jun-Long Niu ; Mao-Ping Song
• 刊名：Organic Letters
• 出版年：2016
• 出版时间：March 18, 2016
• 年：2016
• 卷：18
• 期：6
• 页码：1318-1321
• 全文大小：379K
• ISSN：1523-7052

文摘

A new method of cobalt-catalyzed amination of arylamides with simple alkylamines is reported through C(sp²)–H bond functionalization. For the first time, inexpensive cobalt is exploited as the catalyst in the amination of C(sp²)–H bond using simple alkylamines.