Rational Design of Graphene-Reinforced MnO Nanowires with Enhanced Electrochemical Performance for Li-Ion Batteries

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• 作者：Qi Sun ; Zhijie Wang ; Zijiao Zhang ; Qian Yu ; Yan Qu ; Jingyu Zhang ; Yan Yu ; Bin Xiang
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：March 16, 2016
• 年：2016
• 卷：8
• 期：10
• 页码：6303-6308
• 全文大小：445K
• ISSN：1944-8252

文摘

Recently, transition metal oxides (TMOs) mixed with carbon materials have attracted attention as lithium-ion battery (LIB) anode materials. However, the aggregation issue in TMOs hinders the development of an ideal encapsulation structure with carbon materials. In this paper, we report graphene reinforced MnO nanowires with enhanced electrochemical performance as an anode in LIB. The graphene nanosheets (GNs)/MnO feature was confirmed by transmission electron microscopy, X-ray diffraction, Raman scattering, and X-ray photoelectron spectroscopy. The GNs/MnO nanowires delivered a highly stable discharge capacity of ∼815 mAh g^–1 at a current density of 100 mA g^–1 after 200 cycles, which is 1.5 times higher than that of pure MnO nanowires. This GNs/MnO structure with a specific capacity of ∼995 mAh g^–1 at a current density of 50 mA g^–1 also exhibited excellent Li storage properties. The superior cycling and high rate capability were attributed to the intimate incorporation between the MnO and GNs. The structure of the GNs/MnO nanowires effectively accommodated the volume change of the MnO nanowires and prevented structure collapse during cycling.