Efficient Fabrication of Hierarchically Porous Graphene-Derived Aerogel and Its Application in Lithium Sulfur Battery

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• 作者：Kai Zhang ; Furong Qin ; Yanqing Lai ; Jie Li ; Xiaoke Lei ; Mengran Wang ; Hai Lu ; Jing Fang
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：March 9, 2016
• 年：2016
• 卷：8
• 期：9
• 页码：6072-6081
• 全文大小：738K
• ISSN：1944-8252

文摘

Hierarchically porous carbon/graphene aerogel (CGA) with relatively high surface area and pore volume is synthesized through an efficient fabrication strategy, which involves forming hydrothermal carbon layer on the pore wall as upholder and directly carbonizing the wet hydrogel from hydrothermal reaction, without using any special drying techniques. Cassava powder is used as carbon precursor which enables sustainable synthesis. Carbonizing the wet hydrothermal product is found to be a self-activation process, through which abundant pores are generated. The aerogel is used as host to encapsulate sulfur for lithium sulfur battery. Graphene, served as highly conductive scaffold, accelerates the transport of the electrons. The hierarchically porous structure is in favor of improving the electrochemical performance of lithium sulfur battery. Therefore, the cathode with high sulfur loading and high sulfur content can deliver very good performance.