Self-Assembled Nb2O5 Nanosheets for High Energy–High Power Sodium Ion Capacitors

详细信息    查看全文

• 作者：Hongsen Li ; Yue Zhu ; Shengyang Dong ; Laifa Shen ; Zhijie Chen ; Xiaogang Zhang ; Guihua Yu
• 刊名：Chemistry of Materials
• 出版年：2016
• 出版时间：August 23, 2016
• 年：2016
• 卷：28
• 期：16
• 页码：5753-5760
• 全文大小：492K
• 年卷期：0
• ISSN：1520-5002

文摘

Recently, hybrid ion capacitors which combine the characteristics of batteries and supercapacitors have gained great interests for large-scale energy storage applications. Here, we demonstrated a new hybrid sodium ion capacitor configuration, utilizing the niobium pentoxide (Nb₂O₅) and peanut shell carbon (PSC) as the anode and cathode materials, respectively. The advanced architecture of self-assembled Nb₂O₅ nanosheets with exceptional sodium ion storage property was obtained by carefully controlling reaction kinetics. A key finding is that the growth mechanism is demonstrated to be a process from one-dimensional nanorods to three-dimensional nanocubes, and further to two-dimensional nanosheets. The resulting Nb₂O₅ nanosheets//PSC hybrid capacitors deliver an exceptionally high energy density (43.2 Wh kg^–1) and high power density (5760 W kg^–1) based on the active materials, with a long and stable cycle life (capacity retention: ∼80% at 1280 mA g^–1 after 3000 cycles).