Facile Preparation of Graphene Oxide Membranes for Gas Separation

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• 作者：Chenglong Chi ; Xuerui Wang ; Yongwu Peng ; Yuhong Qian ; Zhigang Hu ; Jinqiao Dong ; Dan Zhao
• 刊名：Chemistry of Materials
• 出版年：2016
• 出版时间：May 10, 2016
• 年：2016
• 卷：28
• 期：9
• 页码：2921-2927
• 全文大小：574K
• 年卷期：0
• ISSN：1520-5002

文摘

We herein report a facile preparation of graphene oxide (GO) membranes including three steps: (1) mild freeze–thaw exfoliation to get large GO nanosheets, (2) purification of exfoliated GO nanosheets through pH adjustment, and (3) spin coating to fabricate smooth GO membranes with uniformly aligned GO nanosheets. The fabricated GO membranes are subject to single gas permeation tests, with the obtained gas permeance in the order He > H₂ ≫ CH₄ > CO₂ > N₂ ≫ SF₆, indicating a dominant molecular sieving separation mechanism. The H₂/CO₂ mixed gas permeation tests reveal H₂ permeance up to 3.4 × 10^–7 mol/(m²·s·Pa) and a H₂/CO₂ separation factor up to 240, which are among the best of all the reported membranes for H₂/CO₂ separation. The separation factor drops to 47 at a higher temperature of 120 °C, but the H₂ permeance is further increased to 6.7 × 10^–7 mol/(m²·s·Pa), ensuring a higher gas separation throughput under higher temperatures. This study paves the way toward large-scale production and application of GO membranes as promising gas separation materials.