Geochemical Characteristics of the Paleogene and Neogene Saline Lacustrine Source Rocks in the Western Qaidam Basin, Northwestern China

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• 作者：Chenglin Liu ; Haohan Li ; Xu Zhang ; Shijing Zheng ; Lin Zhang ; Zeqing Guo ; Jun Liu ; Jixian Tian ; Ying Zhang ; Xu Zeng
• 刊名：Energy & Fuels
• 出版年：2016
• 出版时间：June 16, 2016
• 年：2016
• 卷：30
• 期：6
• 页码：4537-4549
• 全文大小：1023K
• 年卷期：0
• ISSN：1520-5029

文摘

On the basis of salinity and organic geochemical analyses of mudstones, this paper analyzed the relationship between salinity and sedimentary facies of different strata; studied influences of salinity on organic matter richness, types, and thermal maturities of source rocks; and built the organic enrichment accumulation model for the Paleogene and Neogene saline lakes of the western Qaidam Basin. In the western Qaidam Basin, saline lake depocenters and high salinity areas migrated eastward, and chloride ion (Cl^–) concentration of source rocks showed an increasing trend from the Paleocene to Pliocene. The relationship between organic matter content and salinity of the Paleocene and Pliocene source rocks shows a three-interval model: both TOC (total organic carbon) content and chloroform bitumen content have low values at the low salinity stage, first increase to the peak and then decrease to the lowest values at the medium salinity stage, and sustain the lowest values at the super saline stage because of the interaction between organic productivity and reduction–oxidation in the saline lake of the western Qaidam Basin. The relationship between organic matter type and salinity of these source rocks suggests that the kerogen increasingly corresponds to a sapropelic and planktonic origin with increasing salinity. The organic matter enrichment model of the Paleogene and Neogene saline lakes of the western Qaidam Basin showed that saline lakes had high productivity and reducing conditions favorable for organic matter accumulation and preservation at their middle evolution stage. Through improving their apparent activation energy, salinity slowed down thermal evolution of source rocks, making the Paleogene and Neogene source rocks at low maturity to the immature stage in the western Qaidam Basin.