Enhanced CO2 Absorption and Desorption by Monoethanolamine (MEA)-Based Nanoparticle Suspensions

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• 作者：Tao Wang ; Wei Yu ; Fei Liu ; Mengxiang Fang ; Muhammad Farooq ; Zhongyang Luo
• 刊名：Industrial & Engineering Chemistry Research
• 出版年：2016
• 出版时间：July 20, 2016
• 年：2016
• 卷：55
• 期：28
• 页码：7830-7838
• 全文大小：447K
• 年卷期：0
• ISSN：1520-5045

文摘

In this study, three different nanoparticles—SiO₂, TiO₂, and Al₂O₃—were employed to enhance the CO₂ gas absorption by monoethanolamine (MEA) solvent. It is observed that, with increased solids loading, the total mass-transfer enhancement has a tendency to be dominated by the bubble breaking effect. It is concluded that nanoparticles result in an increased CO₂ absorption rate of >10%. On the other hand, nanoparticles exhibit much more attractive impact on CO₂ desorption. Under the same desorption extent, solvent with 0.1 wt % TiO₂ nanoparticles saved 42% desorption time, compared to that without nanoparticles. Under higher heat flux density, more input heat would be supplied to the heat of desorption, rather than the heat of water evaporation, which is due to the enhancement of desorption rate by nanoparticles. The issue of particle aggregation was also investigated by analyzing the size distribution of nanoparticle clusters and zeta potential of MEA solvents.