New Chemical Reaction Process of a Bi2Te2.7Se0.3 Nanomaterial for Feasible Optimization in Transport Properties Resulting in Predominant n-Type Thermoelectric Performance

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• 作者：Cham Kim ; Chang Eun Kim ; Ju Young Baek ; Dong Hwan Kim ; Jong Tae Kim ; Ji Hyeon Ahn ; David Humberto Lopez ; Taewook Kim ; Hoyoung Kim
• 刊名：Industrial & Engineering Chemistry Research
• 出版年：2016
• 出版时间：May 18, 2016
• 年：2016
• 卷：55
• 期：19
• 页码：5623-5633
• 全文大小：723K
• 年卷期：0
• ISSN：1520-5045

文摘

Various chemical reaction processes have been adopted to synthesize Bi₂Te₃ thermoelectric nanomaterials for achieving remarkably low thermal conductivities, but chemical contaminations were usually pointed out as flaws, severely deteriorating electrical conductivities. We devised a novel water-based chemical reaction process for a Bi₂Te_2.7Se_0.3 nanocompound in which the possibility for chemical contaminations was reduced. We successfully synthesized a small and highly distributed Bi₂Te_2.7Se_0.3 nanocompound with high purity and adequately packed it via a spark plasma sintering process to produce a nanobulk structure. The resulting nanobulk specimen exhibited a physical density as high as the theoretical one with highly distributed nanograins; thus, we were able to obtain remarkably high electrical conductivity while maintaining thermal conductivity as low as possible. The synergistic effect was greatly induced between the transport properties; thus, the highest reported figure of merit value was achieved for n-type Bi₂Te₃ in the bulk phase.