Soluble Metal-Nanoparticle-Decorated Porous Coordination Polymers for the Homogenization of Heterogeneous Catalysis

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• 作者：Yuan-Biao Huang ; Qiang Wang ; Jun Liang ; Xusheng Wang ; Rong Cao
• 刊名：Journal of the American Chemical Society
• 出版年：2016
• 出版时间：August 17, 2016
• 年：2016
• 卷：138
• 期：32
• 页码：10104-10107
• 全文大小：252K
• 年卷期：0
• ISSN：1520-5126

文摘

Ultrasmall metal nanoparticles (MNPs) were decorated on soluble porous coordination polymers (PCPs) with high metal loadings. The solubility of the composite and the size of the MNPs can be controlled by varying the ratio of the precursors to the supports. The soluble PCPs can serve as a platform to homogenize heterogeneous MNPs catalysts, which exhibited excellent activity and recyclability in C–H activation and Suzuki reactions. This strategy combines the advantages of homogeneous and heterogeneous catalysis and may bring new inspiration to catalysis.