Pd-Catalyzed C(sp3)–H Functionalization/Carbenoid Insertion: All-Carbon Quaternary Centers via Multiple C–C Bond Formation

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• 作者：Álvaro Gutiérrez-Bonet ; Francisco Juliá-Hernández ; Beatriz de Luis ; Ruben Martin
• 刊名：Journal of the American Chemical Society
• 出版年：2016
• 出版时间：May 25, 2016
• 年：2016
• 卷：138
• 期：20
• 页码：6384-6387
• 全文大小：446K
• 年卷期：0
• ISSN：1520-5126

文摘

A Pd-catalyzed C(sp³)–H functionalization/carbenoid insertion is described. The method allows for the rapid synthesis of bicyclic frameworks, generating all-carbon quaternary centers via multiple C–C bond formations in a straightforward manner.