Inherently Chiral Azonia[6]helicene-Modified β-Cyclodextrin: Synthesis, Characterization, and Chirality Sensing of Underivatized Amino Acids in Water

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• 作者：Qinfei Huang ; Liangwei Jiang ; Wenting Liang ; Jianchang Gui ; Dingguo Xu ; Wanhua Wu ; Yoshito Nakai ; Masaki Nishijima ; Gaku Fukuhara ; Tadashi Mori ; Yoshihisa Inoue ; Cheng Yang
• 刊名：Journal of Organic Chemistry
• 出版年：2016
• 出版时间：April 15, 2016
• 年：2016
• 卷：81
• 期：8
• 页码：3430-3434
• 全文大小：337K
• 年卷期：0
• ISSN：1520-6904

文摘

The (P)- and (M)-3-azonia[6]helicenyl β-cyclodextrins exhibit l/d selectivities of up to 12.4 and P/M preferences of up to 28.2 upon complexation with underivatized proteinogenic amino acids in aqueous solution at pH 7.3.