Structural Characterization, Optical Properties, and Phase Transitions of In1–xSnx Alloy Thin Films

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• 作者：Jinbo Zhang ; Yuxiang Zheng ; Zhanyu Wang ; Songyou Wang ; Rongjun Zhang ; Shangdong Yang ; Dongdong Zhao ; Liao Yang ; Dongxu Zhang ; Liangyao Chen
• 刊名：Journal of Physical Chemistry C
• 出版年：2016
• 出版时间：April 14, 2016
• 年：2016
• 卷：120
• 期：14
• 页码：7822-7828
• 全文大小：498K
• 年卷期：0
• ISSN：1932-7455

文摘

In_1–xSn_x (x = 0.06–0.51) alloy films were deposited on Si substrates by electron beam evaporation and characterized by X-ray diffraction, field-emission scanning electron microscopy, atomic force microscopy, and spectroscopic ellipsometry. The dielectric functions of the In_1–xSn_x alloy films were obtained in the energy range from 1.55 to 4.13 eV based on the spectroscopic ellipsometry measurements, and it is believed that a solid–solid phase transitions led to changes in ε. The phase diagram of nanometer-sized particles is different from that of the bulk material, and this phenomenon can be explained by the surface stress of the particles. The effects of alloying on the electronic band structure were studied from the perspective of first-principles calculations.