Access to Structurally Diverse Quinoline-Fused Heterocycles via Rhodium(III)-Catalyzed C–C/C–N Coupling of Bifunctional Substrates

详细信息    查看全文

• 作者：Songjie Yu ; Yunyun Li ; Xukai Zhou ; He Wang ; Lingheng Kong ; Xingwei Li
• 刊名：Organic Letters
• 出版年：2016
• 出版时间：June 17, 2016
• 年：2016
• 卷：18
• 期：12
• 页码：2812-2815
• 全文大小：373K
• 年卷期：0
• ISSN：1523-7052

文摘

Rhodium(III)-catalyzed C–H activation of heteroarenes and functionalization with bifunctional substrates such as anthranils allows facile construction of quinoline-fused heterocycles under redox-neutral conditions. The couplings feature broad substrate scope and provide step-economical access to two classes of quinoline-fused condensed heterocycles.