Metal-Free Reduction of Aromatic Nitro Compounds to Aromatic Amines with B2pin2 in Isopropanol

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• 作者：Hongtao Lu ; Zhiyue Geng ; Jingya Li ; Dapeng Zou ; Yusheng Wu ; Yangjie Wu
• 刊名：Organic Letters
• 出版年：2016
• 出版时间：June 3, 2016
• 年：2016
• 卷：18
• 期：11
• 页码：2774-2776
• 全文大小：270K
• 年卷期：0
• ISSN：1523-7052

文摘

A metal-free reduction of aromatic nitro compounds to the corresponding amines has been achieved by a combination of B₂pin₂ and KOtBu in isopropanol. A series of nitro compounds containing various reducible functional groups were chemoselectively reduced in good to excellent yields.