Fe-Catalyzed Hydroalkylation of Olefins with para-Quinone Methides

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• 作者：Yangyong Shen ; Jifeng Qi ; Zhenjun Mao ; Sunliang Cui
• 刊名：Organic Letters
• 出版年：2016
• 出版时间：June 3, 2016
• 年：2016
• 卷：18
• 期：11
• 页码：2722-2725
• 全文大小：375K
• 年卷期：0
• ISSN：1523-7052

文摘

A novel Fe-catalyzed hydroalkylation of olefins with para-quinone methides (p-QMs) for accessing phenols has been developed. In this protocol, various olefins could convert to alkyl radicals and undergo addition to para-quinone methides toward C–C bond formation and aromatization. The reaction conditions are mild and the substrate scopes are broad.