Porous Nickel–Iron Selenide Nanosheets as Highly Efficient Electrocatalysts for Oxygen Evolution Reaction

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• 作者：Zhaoyang Wang ; Jiantao Li ; Xiaocong Tian ; Xuanpeng Wang ; Yang Yu ; Kwadwo Asare Owusu ; Liang He ; Liqiang Mai
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：August 3, 2016
• 年：2016
• 卷：8
• 期：30
• 页码：19386-19392
• 全文大小：486K
• 年卷期：0
• ISSN：1944-8252

文摘

Exploring non-noble and high-efficiency electrocatalysts is critical to large-scale industrial applications of electrochemical water splitting. Currently, nickel-based selenide materials are promising candidates for oxygen evolution reaction due to their low cost and excellent performance. In this work, we report the porous nickel–iron bimetallic selenide nanosheets ((Ni_0.75Fe_0.25)Se₂) on carbon fiber cloth (CFC) by selenization of the ultrathin NiFe-based nanosheet precursor. The as-prepared three-dimensional oxygen evolution electrode exhibits a small overpotential of 255 mV at 35 mA cm^–2 and a low Tafel slope of 47.2 mV dec^–1 and keeps high stability during a 28 h measurement in alkaline solution. The outstanding catalytic performance and strong durability, in comparison to the advanced non-noble metal catalysts, are derived from the porous nanostructure fabrication, Fe incorporation, and selenization, which result in fast charge transportation and large electrochemically active surface area and enhance the release of oxygen bubbles from the electrode surface.