Refined Sulfur Nanoparticles Immobilized in Metal–Organic Polyhedron as Stable Cathodes for Li–S Battery

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• 作者：Linyi Bai ; Dongliang Chao ; Pengyao Xing ; Li Juan Tou ; Zhen Chen ; Avijit Jana ; Ze Xiang Shen ; Yanli Zhao
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：June 15, 2016
• 年：2016
• 卷：8
• 期：23
• 页码：14328-14333
• 全文大小：555K
• 年卷期：0
• ISSN：1944-8252

文摘

The lithium–sulfur (Li–S) battery presents a promising rechargeable energy storage technology for the increasing energy demand in a worldwide range. However, current main challenges in Li–S battery are structural degradation and instability of the solid-electrolyte interphase caused by the dissolution of polysulfides during cycling, resulting in the corrosion and loss of active materials. Herein, we developed novel hybrids by employing metal–organic polyhedron (MOP) encapsulated PVP-functionalized sulfur nanoparticles (S@MOP), where the active sulfur component was efficiently encapsulated within the core of MOP and PVP as a surfactant was helpful to stabilize the sulfur nanoparticles and control the size and shape of corresponding hybrids during their syntheses. The amount of sulfur embedded into MOP could be controlled according to requirements. By using the S@MOP hybrids as cathodes, an obvious enhancement in the performance of Li–S battery was achieved, including high specific capacity with good cycling stability. The MOP encapsulation could enhance the utilization efficiency of sulfur. Importantly, the structure of the S@MOP hybrids was very stable, and they could last for almost 1000 cycles as cathodes in Li–S battery. Such high performance has rarely been obtained using metal–organic framework systems. The present approach opens up a promising route for further applications of MOP as host materials in electrochemical and energy storage fields.