Co(II)1–xCo(0)x/3Mn(III)2x/3S Nanoparticles Supported on B/N-Codoped Mesoporous Nanocarbon as a Bifunctional Electrocatalyst of Oxygen Reduction/Evolution for High-Performance Zinc-Air Batteries

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• 作者：Zilong Wang ; Shuang Xiao ; Yiming An ; Xia Long ; Xiaoli Zheng ; Xihong Lu ; Yexiang Tong ; Shihe Yang
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：June 1, 2016
• 年：2016
• 卷：8
• 期：21
• 页码：13348-13359
• 全文大小：715K
• 年卷期：0
• ISSN：1944-8252

文摘

Rechargeable Zn-air battery is an ideal type of energy storage device due to its high energy and power density, high safety, and economic viability. Its large-scale application rests upon the availability of active, durable, low-cost electrocatalysts for the oxygen reduction reaction (ORR) in the discharge process and oxygen evolution reaction (OER) in the charge process. Herein we developed a novel ORR/OER bifunctional electrocatalyst for rechargeable Zn-air batteries based on the codoping and hybridization strategies. The B/N-codoped mesoporous nanocarbon supported Co(II)_1–xCo(0)_x/3Mn(III)_2x/3S nanoparticles exhibit a superior OER performance compared to that of IrO₂ catalyst and comparable Zn-air battery performance to that of the Pt-based battery. The rechargeable Zn-air battery shows high discharge peak power density (over 250 mW cm^–2) and current density (180 mA cm^–2 at 1 V), specific capacity (∼550 mAh g^–1), small charge–discharge voltage gap of ∼0.72 V at 20 mA cm^–2 and even higher stability than the Pt-based battery. The advanced performance of the bifunctional catalysts highlights the beneficial role of the simultaneous formation of Mn(III) and Co(0) as well as the dispersed hybridization with the codoped nanocarbon support.