Biomass-Based Mechanically Strong and Electrically Conductive Polymer Aerogels and Their Application for Supercapacitors

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• 作者：Hai-Bo Zhao ; Lei Yuan ; Zhi-Bing Fu ; Chao-Yang Wang ; Xi Yang ; Jia-Yi Zhu ; Jing Qu ; Hong-Bing Chen ; David A. Schiraldi
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：April 20, 2016
• 年：2016
• 卷：8
• 期：15
• 页码：9917-9924
• 全文大小：538K
• 年卷期：0
• ISSN：1944-8252

文摘

A novel biomass-based mechanically strong and electrically conductive polymer aerogel was fabricated from aniline and biodegradable pectin. The strong hydrogen bonding interactions between polyaniline (PANI) and pectin resulted in a defined structure and enhanced properties of the aerogel. All the resultant aerogels exhibited self-surppoted 3D nanoporous network structures with high surface areas (207–331m²/g) and hierarchical pores. The results from electrical conductivity measurements and compressive tests revealed that these aerogels also had favorable conductivities (0.002–0.1 S/m) and good compressive modulus (1.2–1.4 MPa). The aerogel further used as electrode for supercapacitors showed enhanced capacitive performance (184 F/g at 0.5 A/g). Over 74% of the initial capacitance was maintained after repeating 1000 cycles of the cylic voltammetry test, while the capacitance retention of PANI was only 57%. The improved electrochemical performance may be attributed to the combinative properties of good electrical conductivity, BET surface areas, and stable nanoporous structure of the aerogel. Thus, this aerogel shows great potential as electrode materials for supercapacitors.