Bacteria Absorption-Based Mn2P2O7–Carbon@Reduced Graphene Oxides for High-Performance Lithium-Ion Battery Anodes

详细信息    查看全文

• 作者：Yuhua Yang ; Bin Wang ; Jingyi Zhu ; Jun Zhou ; Zhi Xu ; Ling Fan ; Jian Zhu ; Ramakrishna Podila ; Apparao M. Rao ; Bingan Lu
• 刊名：ACS Nano
• 出版年：2016
• 出版时间：May 24, 2016
• 年：2016
• 卷：10
• 期：5
• 页码：5516-5524
• 全文大小：619K
• 年卷期：0
• ISSN：1936-086X

文摘

The development of freestanding flexible electrodes with high capacity and long cycle-life is a central issue for lithium-ion batteries (LIBs). Here, we use bacteria absorption of metallic Mn²⁺ ions to in situ synthesize natural micro-yolk–shell-structure Mn₂P₂O₇–carbon, followed by the use of vacuum filtration to obtain Mn₂P₂O₇–carbon@reduced graphene oxides (RGO) papers for LIBs anodes. The Mn₂P₂O₇ particles are completely encapsulated within the carbon film, which was obtained by carbonizing the bacterial wall. The resulting carbon microstructure reduces the electrode–electrolyte contact area, yielding high Coulombic efficiency. In addition, the yolk–shell structure with its internal void spaces is ideal for sustaining volume expansion of Mn₂P₂O₇ during charge/discharge processes, and the carbon shells act as an ideal barrier, limiting most solid–electrolyte interphase formation on the surface of the carbon films (instead of forming on individual particles). Notably, the RGO films have high conductivity and robust mechanical flexibility. As a result of our combined strategies delineated in this article, our binder-free flexible anodes exhibit high capacities, long cycle-life, and excellent rate performance.