Top Laminated Graphene Electrode in a Semitransparent Polymer Solar Cell by Simultaneous Thermal Annealing/Releasing Method

详细信息    查看全文

• 作者：Yu-Ying Lee ; Kun-Hua Tu ; Chen-Chieh Yu ; Shao-Sian Li ; Jeong-Yuan Hwang ; Chih-Cheng Lin ; Kuei-Hsien Chen ; Li-Chyong Chen ; Hsuen-Li Chen ; Chun-Wei Chen
• 刊名：ACS Nano
• 出版年：2011
• 出版时间：August 23, 2011
• 年：2011
• 卷：5
• 期：8
• 页码：6564-6570
• 全文大小：939K
• 年卷期：0
• ISSN：1936-086X

文摘

In this article, we demonstrate a semitransparent inverted-type polymer solar cell using a top laminated graphene electrode without damaging the underlying organic photoactive layer. The lamination process involves the simultaneous thermal releasing deposition of the graphene top electrode during thermal annealing of the photoactive layer. The resulting semitransparent polymer solar cell exhibits a promising power conversion efficiency of approximately 76% of that of the standard opaque device using an Ag metal electrode. The asymmetric photovoltaic performances of the semitransparent solar cell while illuminated from two respective sides were further analyzed using optical simulation and photocarrier recombination measurement. The devices consisting of the top laminated transparent graphene electrode enable the feasible roll-to-roll manufacturing of low-cost semitransparent polymer solar cells and can be utilized in new applications such as power-generated windows or multijunction or bifacial photovoltaic devices.