A (3,6)-Connected Metal–Organic Framework with pyr Topology and Highly Selective CO2 Adsorption

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• 作者：Qian Wang ; Jingjing Jiang ; Mingxing Zhang ; Junfeng Bai
• 刊名：Crystal Growth & Design
• 出版年：2017
• 出版时间：January 4, 2017
• 年：2017
• 卷：17
• 期：1
• 页码：16-18
• 全文大小：309K
• ISSN：1528-7505

文摘

Upon the basis of a bifunctional organic ligand with two carboxyl groups and one N donor, 5-(quinolin-4-yl)isophthalic acid (H₂L), a new (3,6)-connected metal–organic framework with pyr topology, [Cu(L)·DMF]_n (NJU-Bai32), has been synthesized and exhibits highly selective CO₂ adsorption.