Iodine-Rich Imidazolium Iodate and Periodate Salts: En Route to Single-Based Biocidal Agents

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• 作者：Chunlin He ; Joseph P. Hooper ; Jean’ne M. Shreeve
• 刊名：Inorganic Chemistry
• 出版年：2016
• 出版时间：December 19, 2016
• 年：2016
• 卷：55
• 期：24
• 页码：12844-12850
• 全文大小：357K
• ISSN：1520-510X

文摘

Two classes of iodine-rich salts that consist of iodine-rich cations and iodate (IO₃^–) or periodate (IO₄^–) anions were synthesized. The synthesis of analogous I₃O₈^– salts was more difficult because of poor solubility and hydrolytic instability. All iodine-rich salts were fully characterized by infrared, ¹H nuclear magnetic resonance, and ¹³C nuclear magnetic resonance spectroscopy as well as elemental analyses. The molecular structures of compounds 15 and 24 were elucidated by X-ray single-crystal diffraction. Additionally, the heats of formation were calculated with Gaussian 03. The detonation properties and biocidal efficiency were calculated and evaluated using CHEETAH 7.