All-Inorganic Perovskite Solar Cells

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• 作者：Jia Liang ; Caixing Wang ; Yanrong Wang ; Zhaoran Xu ; Zhipeng Lu ; Yue Ma ; Hongfei Zhu ; Yi Hu ; Chengcan Xiao ; Xu Yi ; Guoyin Zhu ; Hongling Lv ; Lianbo Ma ; Tao Chen ; Zuoxiu Tie ; Zhong Jin ; Jie Liu
• 刊名：Journal of the American Chemical Society
• 出版年：2016
• 出版时间：December 14, 2016
• 年：2016
• 卷：138
• 期：49
• 页码：15829-15832
• 全文大小：322K
• ISSN：1520-5126

文摘

The research field on perovskite solar cells (PSCs) is seeing frequent record breaking in the power conversion efficiency (PCE). However, organic–inorganic hybrid halide perovskites and organic additives in common hole-transport materials (HTMs) exhibit poor stability against moisture and heat. Here we report the successful fabrication of all-inorganic PSCs without any labile or expensive organic components. The entire fabrication process can be operated in ambient environment without humidity control (e.g., a glovebox). Even without encapsulation, the all-inorganic PSCs present no performance degradation in humid air (90–95% relative humidity, 25 °C) for over 3 months (2640 h) and can endure extreme temperatures (100 and −22 °C). Moreover, by elimination of expensive HTMs and noble-metal electrodes, the cost was significantly reduced. The highest PCE of the first-generation all-inorganic PSCs reached 6.7%. This study opens the door for next-generation PSCs with long-term stability under harsh conditions, making practical application of PSCs a real possibility.