Graphene/MWNT/Poly(p-phenylenebenzobisoxazole) Multiphase Nanocomposite via Solution Prepolymerization with Superior Microwave Absorption Properties and Thermal Stability

详细信息    查看全文

• 作者：Jiasong HuaYanxiao Li ; Xiaoyun Liu ; Xinxin Li ; Shaoliang Lin ; Jinlou Gu ; Zhong-Kai Cui ; Qixin Zhuang
• 刊名：Journal of Physical Chemistry C
• 出版年：2017
• 出版时间：January 19, 2017
• 年：2017
• 卷：121
• 期：2
• 页码：1072-1081
• 全文大小：838K
• ISSN：1932-7455

文摘

This paper demonstrates both the high-performance microwave absorption properties and the superior thermal stability of graphene/multiwalled carbon nanotubes (MWNTs)/poly(p-phenylenebenzobisoxazole) (PBO) composites synthesized via in situ polymerization of functionalized PBO precursor with graphene oxide/MWNTs nanocomposites, followed by high-temperature calcination. The incorporation of three-dimensional graphene/MWNTs network significantly improved the reflection loss of PBO composites (−50.17 dB at 12.58 GHz) by over 20 times than that of pure PBO (−2.33 dB at 12.58 GHz) with a sample thickness of only 2.6 mm. The effect of graphene/MWNTs content on the microwave absorption performance was also investigated. The graphene/MWNTs/PBO composite shows great promise as a microwave absorber in high-temperature environments.