Tetracarboxylated Azobenzene/Polymer Supramolecular Assemblies as High-Performance Multiresponsive Actuators

详细信息    查看全文

• 作者：Chengqun Qin ; Yiyu Feng ; Haoran An ; Junkai Han ; Chen Cao ; Wei Feng
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2017
• 出版时间：February 1, 2017
• 年：2017
• 卷：9
• 期：4
• 页码：4066-4073
• 全文大小：540K
• ISSN：1944-8252

文摘

Multistimuli-responsive polymers are materials of emerging interest but synthetically challenging. In this work, supramolecular assembly was employed as a facile and effective approach for constructing 3,3′,5,5′-azobenzenetetracarboxylic acid (H₄abtc)/poly(diallyldimethylammonium chloride) (PDAC) supramolecules. Structural transformations of H₄abtc can be induced by light, mechanical force, and heat and influenced by free volume. Thus, the fabricated free-standing H₄abtc/PDAC film underwent bending/unbending movements upon treatment with light, humidity, or temperature, as asymmetric structural transformations on either side of the film generated asymmetric contraction/stretching forces. Fast rates of shape recovery were achieved for the film on exposure to gently flowing humid nitrogen. The bending/unbending motions are controllable, reversible, and repeatable. Hence, this light-, humido-, and thermo-responsive film has great potential in device applications for advanced functions.